NON-ISOTHERMAL CRYSTALLIZATION BEHAVIOR OF BIODEGRADABLE POLY(BUTYLENE SUCCINATE-CO- -TEREPHTHALATE) (PBST) COPOLYESTERS

Abstract

Non-isothermal crystallization and subsequent melting of biodegradable poly(butylene uccinate-co-terephthalate) copolyesters with different butylene terephthalate ontents were investigated by differential scanning calorimetry measurements. ifferential scanning calorimetry crystallization curves revealed that butylene erephthalate contents of poly(butylene succinate-co-terephthalate) copolyesters ad an identical effects on the onset, peak and final crystallization temperatures. ubsequent differential scanning calorimetry melting curves implied hat both PBST-10 and PBST-70 copolyesters had the narrow distribution of lamellar hickness, while the PBST-50 copolyester showed much wider distribution.

Dates

  • Submission Date2012-08-15
  • Revision Date2012-09-01
  • Acceptance Date2012-09-12

DOI Reference

10.2298/TSCI1205480Z

References

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  2. Li, F. X., et al., Effects of Comonomer Sequential Structure on Thermal and Crystallization Behaviors of Biodegradable Poly(Butylene Succinate-Co-Butylene Terephthalate)s, Journal of Polymer Science Part B: Polymer Physics, 44 (2006), 12, pp. 1635-1644
  3. Li, F. X., et al., The Morphological Effects upon Enzymatic Degradation of Poly (Butylene Succinate- Co-Butylene Terephthalate) (PBST), Polymer Degradation and Stability, 92 (2007), 6, pp. 1053-1060
  4. Li, F. X., et al., The Crystallization and Morphology of Biodegradable Poly (Butylene Succinate-Co- Terephthalate) Copolyesters with High Content of BT Units, Journal of Applied Polymer Science, 118 (2010), 2, pp. 623-630
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