NON-ISOTHERMAL CRYSTALLIZATION BEHAVIOR OF BIODEGRADABLE POLY(BUTYLENE SUCCINATE-CO- -TEREPHTHALATE) (PBST) COPOLYESTERS
Abstract
Non-isothermal crystallization and subsequent melting of biodegradable poly(butylene
uccinate-co-terephthalate) copolyesters with different butylene terephthalate
ontents were investigated by differential scanning calorimetry measurements.
ifferential scanning calorimetry crystallization curves revealed that butylene
erephthalate contents of poly(butylene succinate-co-terephthalate) copolyesters
ad an identical effects on the onset, peak and final crystallization temperatures.
ubsequent differential scanning calorimetry melting curves implied
hat both PBST-10 and PBST-70 copolyesters had the narrow distribution of lamellar
hickness, while the PBST-50 copolyester showed much wider distribution.
Dates
- Submission Date2012-08-15
- Revision Date2012-09-01
- Acceptance Date2012-09-12
References
- Shi, X. Q., et al., Characterization on Mixed-Crystal Structure of Poly (Butylene Terephthalate/Succinate/ Adipate) Biodegradable Copolymer Fibers, Polymer, 46 (2005), 3, pp. 751-760
- Li, F. X., et al., Effects of Comonomer Sequential Structure on Thermal and Crystallization Behaviors of Biodegradable Poly(Butylene Succinate-Co-Butylene Terephthalate)s, Journal of Polymer Science Part B: Polymer Physics, 44 (2006), 12, pp. 1635-1644
- Li, F. X., et al., The Morphological Effects upon Enzymatic Degradation of Poly (Butylene Succinate- Co-Butylene Terephthalate) (PBST), Polymer Degradation and Stability, 92 (2007), 6, pp. 1053-1060
- Li, F. X., et al., The Crystallization and Morphology of Biodegradable Poly (Butylene Succinate-Co- Terephthalate) Copolyesters with High Content of BT Units, Journal of Applied Polymer Science, 118 (2010), 2, pp. 623-630
Volume
16,
Issue
5,
Pages1480 -1483