NOx and SO2 emission factors for Serbian lignite Kolubara

Abstract

Emission factors are widely accepted tool for estimation of various ollutants emissions in USA and EU. Validity of emission factors is strongly elated to experimental data on which they are based. This paper is a result f an effort to establish reliable NOx and SO2 emission factors for Serbian oals. The results of NOx and SO2 emissions estimations based on USA and U emission factors from thermal power plants Nikola Tesla Obrenovac A nd B utilizing the Serbian lignite Kolubara are compared with experimental ata obtained during almost one decade (2000-2008) of emissions easurements. Experimental data are provided from regular annual missions measurement along with operational parameters of the boiler and oal (lignite Kolubara) ultimate and proximate analysis. Significant eviations of estimated from experimental data were observed for NOx, while he results for SO2 were satisfactory. Afterwards, the estimated and xperimental data were plotted and linear regression between them stablished. Single parameter optimization was performed targeting the deal slope of the regression line. Results of this optimization provided riginal NOx and SO2 emission factors for Kolubara lignite.

Dates

  • Submission Date2012-03-19
  • Revision Date2012-03-28
  • Acceptance Date2012-03-30

DOI Reference

10.2298/TSCI120319055J

References

  1. ***, EMEP/EEA air pollutant emission inventory guidebook 2009, Technical guidance to prepare national emission inventories, European Environment Agency, Copenhagen, 2009, ISBN 978-92-9213-034-3.
  2. ***, Step by step guideline for emission calculation, record keeping and reporting for airborne contaminant discharge, Ontario Ministry of the Environment, Ontario, 2004.
  3. Nelson, P., Coal nitrogen & NOx, ACARP Report No. 01, Australian Coal Association Research Program, Australia, 2006.
  4. Mereb, B., Assessing the effects of coal properties on NOx emissions in combustion systems. In: EPRI-DOE-EPA combined air pollution control symposium: the MEGA symposium, Vol.2: NOx and multi-pollutant controls, Atlanta, GA, USA, 16-20 Aug 1999. EPRI-TR-113187-V2, Palo Alto, CA, USA, pp 14.1-14.14, 1999.
  5. ***, Procedures For Preparing Emission Factor Documents, EPA-454/R-95-015, USEPA, 1997.
  6. Bozanic, D., Gasperic, M., (editors), Initial National Communication of the Republic of Serbia under the United Nations Framework Convention on Climate Change, The Ministry of Environment and Spatial Planning, Republic of Serbia, Belgrade, 2010.
  7. Stojiljkovic, D., Radovanovic, M., Ercegovac, M., Jones J., Williams A.: Devolatilisation and Combustion of Yugoslav Lignites; Journal of the Energy Institute, Vol. 78, No. 4 (1-6), 2005.
  8. Mladenovic, M., Mladenovic, R., Manovic, V., Radovanovic, M., Stojiljkovic, D., Criteria selection for the assessment of Serbian lignites tendency to form deposits on power boilers heat transfer surfaces, Thermal Science Vol. 13 No.4 pp. 61-78, 2009.
  9. Laban, K., Atkin, B., The direct determination of the forms of sulphur in coal using microwave digestion and i.c.p-a.e.s analysis, Fuel Vol. 79 Issue 2, pp.173-180, 2000.
  10. Davidson, R., Quantifying organic sulfur in coal: A review, Fuel, Volume 73, Issue 7, pp. 988- 1005, 1994.
  11. Singer, G., Control of power-plant stack emissions. In: Combustion fossil power, Singer J G (ed), Windsor, CT, USA, Combustion Engineering Inc., pp. 15.1-15.76, 1991.
  12. Okamoto, A., Evaluation of thermal coal quality (Japan) (III), Coal and Safety No. 12, pp. 18- 39, 1998.
  13. McInnes G (ed) (1996) Joint EMEP/CORINAIR atmospheric emission inventory guidebook. First ed. Copenhagen, Denmark, European Environment Agency, CD-ROM (Feb 1996)
  14. Davidson, M., Nitrogen in coal, IEAPER/08, London, UK, IEA Coal Research, 1994.
  15. ***, Preferred and Alternative Methods For Estimating Air Emissions From Boilers, Eastern Research Group Inc., 2001
  16. Eggleston H.S., Buendia L., Miwa K., Ngara T. and Tanabe K. (eds)., IPCC Guidelines for National Greenhouse Gas Inventories, IGES, Japan, 2006.
  17. ***, EMEP/EEA air pollutant emission inventory guidebook 2009 Technical guidance to prepare national emission inventories, EEA Technical report No 9/2009, EEA, 2009.
  18. ***, Regulation on emission limit values (ELV), method and terms of measurement and data recording published in Official Gazette RS 30/97, Belgrade, 1997.
  19. ***, AP-42, Compilation of Air Pollutant Emission Factors, Volume I, Stationary Point and Area Sources, Fifth Edition, 1997.
  20. ***, Single measurements of hazardous and toxic matter emissions in air from Unit A4 of TPP Nikola Tesla A in 2000, Mining Institute - Belgrade, Department for HVAC and environmental protection, Belgrade, 2001.
  21. ***, Single measurements of hazardous and toxic matter emissions in air from Unit A1 of TPP Nikola Tesla A in 2002, Mining Institute - Belgrade, Department for HVAC and environmental protection, Belgrade, 2003.
  22. ***, Single measurements of hazardous and toxic matter emissions in air from Unit B1 of TPP Nikola Tesla B in 2003, Mining Institute - Belgrade, Department for HVAC and environmental protection, Belgrade, 2004.
  23. ***, Single measurements of hazardous and toxic matter emissions in air from Unit B2 of TPP Nikola Tesla B in 2003, Mining Institute - Belgrade, Department for HVAC and environmental protection, Belgrade, 2004.
  24. ***, Single measurements of hazardous and toxic matter emissions in air from Unit B2 of TPP Nikola Tesla B in 2008, Mining Institute - Belgrade, Laboratory for environmental protection, Belgrade, 2008.
Volume 16, Issue 4, Pages1213 -1228